Miyagi High School 3rd Years Daichi Sawamura / Captain, WS (Wing Spiker) Koushi Sugawara / Vice-Captain, S (Setter) Asahi Azumane / WS, Ace Kiyoko Shimizu / Manager 2nd Years Yuu Nishinoya / Li (Libero) Ryuunosuke Tanaka / WS Chikara Ennoshita / WS Hisashi Kinoshita / WS Kazuhito Narita / MB 1st Years Shouyou Hinata / MB Tobio Kageyama / S Kei Tsukishima / MB Tadashi Yamaguchi / MB Hitoka Yachi / Manager Ittetsu Takeda / Advisor & Head Coach Keishin Ukai / Coach Ikkei Ukai / Former Head Coach Makoto Shimada / Alumnus Saeko Tanaka / Alumna Akiteru Tsukishima / Alumnus Tenma Udai / Alumnus

Tokyo High School 3rd Years Tetsurou Kuroo / Captain, MB (Middle Blocker) Nobuyuki Kai / Vice-Captain, WS (Wing Spiker) Morisuke Yaku / Li (Libero) 2nd Years Kenma Kozume / S Taketora Yamamoto / WS Shohei Fukunaga / WS 1st Years Lev Haiba / MB Sou Inuoka / MB Yuuki Shibayama / Li Tamahiko Teshiro / S Yasufumi Nekomata / Advisor & Head Coach Manabu Naoi / Coach

Tokyo High School 3rd Years Koutarou Bokuto / Captain, WS Akinori Konoha / WS Yamato Sarukui / WS Haruki Komi / Li Tatsuki Washio / MB Kaori Suzumeda / Manager Yukie Shirofuku / Manager 2nd Years Keiji Akaashi / Vice-Captain, S 1st Years Wataru Onaga / MB Takeyuki Yamiji / Advisor & Head Coach

Hyogo High School 3rd Years Shinsuke Kita / Captain, WS - Possesses an indomitable spirit and strong character Aran Ojiro / WS Ren Omimi / MB Michinari Akagi / Li 2nd Years Atsumu Miya / S - "High School's No. 1 Setter" Osamu Miya / WS Rintarou Suna / MB Hitoshi Ginjima / WS 1st Years Heisuke Riiseki / WS Norimune Kurosu / Advisor & Head Coach

Miyagi High School 3rd Years Wakatoshi Ushijima / Captain, WS - Possesses overwhelming power and spikes from high angles as a lefty. One of the top three aces in the nation. Alias: "The Absolute Champion" Satori Tendou / MB - A master of "Guess Blocking," predicting the trajectory of spikes through intuition and sharp reading. Alias: "The Guess Monster" Leon Ohira / WS Hayato Yamagata / Li Eita Semi / S 2nd Years Kenjirou Shirabu / S Taichi Kawanishi / MB 1st Years Tsutomu Goshiki / WS Yuushou Sagae / WS Kai Akakura / Li Tanji Washijou / Advisor & Head Coach

Miyagi High School 3rd Years Tooru Oikawa / Captain, S Hajime Iwaizumi / Vice-Captain, WS (Wing Spiker) Issei Matsukawa / MB Takahiro Hanamaki / WS Kaname Shigeta / WS Motomu Sawauchi / MB Heisuke Shido / WS 2nd Years Shinji Watari / Li Shigeru Yahaba / S Kentaro Kyotani / WS 1st Years Yuutarou Kindaichi / MB Akira Kunimi / WS Nobuteru Irimata / Advisor & Head Coach Sadayuki Mizoguchi / Coach

Nagano High School 3rd Years Aikichi Suwa / Captain, S Izuru Nozawa / WS Keiichiro Kanbayashi / Li 2nd Years Kourai Hoshiumi / WS - An all-rounder who combines incredible jumping power, speed, and power despite his small stature. Can hit any course. "The Little Giant" Sachirou Hirugami / MB - Despairs opponents with overwhelming blocking technique. Alias: "Hirugami the Immovable" Gao Hakuba / WS - Weapons include spikes and blocks from a high vantage point, utilizing his massive frame of over 2 meters. 1st Years Chigaya Bessho / MB Aaron Murphy / Advisor & Head Coach

Tokyo High School 3rd Years Tsukasa Iizuna / Captain, S 2nd Years Kiyoomi Sakusa / WS - Uses his natural wrist flexibility to apply spin, making his spikes difficult to receive. Motoya Komori / Li - "High School's No. 1 Libero." Sakusa's cousin.

Oita High School 3rd Years Wakatsu Kiryu / Captain, WS - One of the top three aces in the nation. Alias: "Kiryu the Bad-Ball Hitter" Keisuke Unnan / MB - The cornerstone of Kiryu High's block. Naoharu Ezota / WS 2nd Years Michiru Usuri / S Subaru Hondo / WS Michiko Kudo / Advisor & Head Coach