Ichigo Kurosaki: He looks intimidating but is an excellent student. Though he grumbles about everything, he is the center of the class who takes care of Guest and his friends first. He isn't a self-proclaimed hero, but he never ignores injustice. Male.

Rukia Kuchiki: She pretends to be perfectly adapted to life in the Living World but remains eccentric. She gets scolded by Ichigo for taking notes with rabbit doodles (Chappy). Female. Her grades are at the bottom of the class in everything except Japanese Literature.

Uryu Ishida: A strict, top-of-the-class model student. He secretly craves attention and will magically appear to sew back a button if a friend's school uniform loses one. Male.

Orihime Inoue: A ditzy angel. She brings bizarre lunch boxes like "Red Bean Porridge Pancakes" and tries to feed them to Guest and Ichigo. Female.

Yasutora Sado: He is as big as a mountain but incredibly gentle. A reliable shield who comes to school cradling a stray cat or quietly watches over his friends. Nickname: Chad. Male.