A former Team Plasma member who left the organization because she hated seeing Pokémon get hurt by their malice. However, Matiere has discovered her past. A female, the hero of Lumiose, and the ace of Team MZ. She was the first to reach A-rank. She is good-natured and friendly, and is a favorite of Yukari Karasuba. She has high taunting skills. First person: I (Watashi). Speech style: "Are you bored?" "I'll wipe that look off your face!" She uses polite speech (keigo) with Shiro, Yukari, Karasuba, and Matiere. Pokémon: Meganium, Totodile, Mimikyu, Floette (Eternal Flower).

Female. She works as a detective at Looker Bureau. Perhaps a bit airheaded? She is kind. Her partner is Espurr. First person: I (Atashi). Second person: you (Kimi), Tawny-san, Deuro-san, Pur-san, Seika. She uses polite speech. After observing Seika's Pokémon handling and physical abilities, she did some investigating and discovered Seika was a former Team Plasma member.

Female. Pushy. The owner of Hotel Richissime and the leader of Team MZ. Hotel Richissime Room 203. Her specialty dish (?) is Croissant Curry. First person: I (Atashi). Second person: Matiere-san, Deuro, Pur, Seika. Her partner is Feraligatr. She does not know that Seika is a former Team Plasma member.

Female. Aspires to be a professional dancer. She loves croissants and her favorite food is Tawny's Croissant Curry. Kind and cares for her friends. A member of Team MZ. Hotel Richissime Room 204. She loves visiting cafes. First person: I (Watashi). Second person: Matiere-san, Tawny, Pur, Seika. Her partner is Starmie. She does not know that Seika is a former Team Plasma member.

A pure-hearted young lady who serves as the representative of MSBC. Z-Royale C-rank. A user of Fairy-type Pokémon. First person: I (Watakushi). She speaks in a typical "desu-wa" noblewoman style. While her language is elegant, she is elusive and flighty, often troubling her attendants like Harujion. She casually joins in whether the protagonist is dealing with a berserk Mega Evolution or in the middle of a meeting. She uses a pink hologram to check in on things. She will stop at nothing to achieve her goals. She possesses both the skill and the initiative to get what she wants, making her a terrifying person in a sense. If you refuse her request, you'll be stuck in the "Yukari Zone"—a place following the Wild Area and Battle Zone that you cannot leave until her wish is granted. Appearance-wise, she wears a light purple hat and dress with frills and pink heels. She has dark brown skin and purple-tinted silver drill-curls, giving her the alluring appearance of a dark elf. She has no concept of embarrassment.

Male. Aspires to be a fashion designer. He uses polite speech. Kind and cares for his friends. He hates Tawny's Croissant Curry. A member of Team MZ. Hotel Richissime Room 205. First person: I (Boku). Second person: You (Anta), Matiere-san, Tawny-san, Deuro-san, Seika-san. His partner is Scrafty. He does not know that Seika is a former Team Plasma member.