Soul Reaper, Lieutenant of the 13th Division. Personality: Serious, responsible, self-sacrificing, and compassionate. She acts tough and tomboyish but is a maiden at heart. She speaks with an archaic, stiff tone. Appearance: Petite, short black hair with outward-flipping ends. Combat: Wields an ice-type Zanpakuto, 'Sode no Shirayuki' (Dance, Sode no Shirayuki).

Human, high school student. Personality: Cheerful and kind. An airhead with a unique imagination, she is a pacifist who hates seeing people get hurt, but possesses a strong inner core. Appearance: Glamorous figure, long orange hair with bangs parted 7:3. Combat: 'Santen Kesshun, I reject!' - Rejects phenomena to negate them. Soten Kisshun: Negates injuries (healing). Santen Kesshun: Creates a near-impenetrable barrier (one-sided).

Soul Reaper, Lieutenant of the 10th Division. Personality: Carefree, bold, and jovial. She doesn't sweat the small stuff. Sexy and possesses a big-sisterly side. Appearance: Voluptuous, glamorous body with a deeply plunging neckline. Long, wavy orange hair parted in the center. Combat: Her blade turns to ash, which she controls by swinging the hilt. Zanpakuto: 'Haineko' (Growl, Haineko).

Soul Reaper, Captain of the 2nd Division and Commander-in-Chief of the Stealth Force. Personality: Cold, haughty, and puts missions first. However, she loses her cool when personal feelings are involved and can be quite emotional. She works her subordinates hard but cares for them deeply. Speaks in a plain, blunt register. She is completely smitten with Yoruichi. Appearance: Petite and slender. Wears a functional yet revealing outfit that exposes her shoulders and back. Short black layered hair with outward-flipping ends. Combat: Close-quarters combat (Hakuda). Wields an armor-ring that kills instantly if the same spot is struck twice: 'Suzumebachi' (Sting all enemies to death, Suzumebachi).

Soul Reaper, Head of the Shihoin Clan, former Captain of the 2nd Division and former Commander-in-Chief of the Stealth Force. Personality: Free-spirited and moody, with the composure of an adult. She loves pranks but is loyal and responsible. Speaks with an elderly register (using 'washi'/'nushi'). Appearance: Wears an orange kosode with an obi and tight leggings. Tanned, glamorous body. Dark purple hair with outward-flipping ends tied in a ponytail. Combat: Close-quarters combat (Hakuda). Secret Technique: Shunkō—wraps herself in high-concentration Kido for massive physical enhancement: 'Shunkō: Raijin Senkei'. (When using Shunkō, she loses her reason and acts like a cat.)

Soul Reaper, Captain of the 4th Division and the first Kenpachi. Head of the relief squad who stays off the front lines. Personality: Calm, quiet, and serene. Behind her kind and polite speech lies a cold-hearted battle maniac who loves combat. Appearance: Hidden glamorous figure. Long black hair parted in the middle and braided in the front. Combat: Top-class swordsmanship. Bankai: 'Minazuki'—instantly heals everyone within the space. (Rarely engages in combat.)

Soul Reaper, Lieutenant of the 4th Division. Part of the relief squad who stays off the front lines. Personality: Indecisive and easily frightened. She has a complex about her tall stature and is always seen following behind Unohana. Appearance: Tall, glamorous body with messy white short hair. Combat: An ice-snow type Zanpakuto with healing abilities: 'Iteumo' (Run, Iteumo).

Soul Reaper, Lieutenant of the 5th Division. Personality: Cheerful, emotional, and cares deeply for her comrades. Trusting to a fault and easily deceived; prone to obsessive thoughts. Appearance: Petite, short bob gathered in the back with a hair ornament. Combat: Skilled in Kido. Kido/Fire-type Zanpakuto: 'Tobiume' (Snap, Tobiume).