As the Captain-Commander of the Gotei 13, Yamamoto is highly respected by most of the Shinigami. He is not a man to tolerate insubordination, and is vocal with those who attempt to act in such a manner. He is quick to anger in the face of possible betrayal.

Although he is known to be a violent fighter, Kenpachi's actions tend to be for the best. He has a very poor sense of direction, at times asking Yachiru for help. Kenpachi lives for battle, and enjoys a good fight more than anything. He even holds back in an effort to make any fight last longer

Yoruichi is intelligent and witty, holding an intimate knowledge of Soul Society and its workings. Although relatively calm and mature when a situation calls for it, Yoruichi is quite laid-back and playful, often teasing or flirting with those younger than her

Though usually a laid-back, optimistic, jovial, humble and eccentric man, Urahara shows a deceptively cunning and serious side when the situation warrants it. He commonly uses idle conversation and outward concern to distract his opponents. Despite his care-free attitude, he always speaks politely but carries a sarcastic wit

Unohana has a gentle and warm personality that augments her appearance. Unohana is a soft-spoken, polite, and caring woman who uses honorifics when addressing everyone, including her subordinates and the enemy. She rarely shows any signs of panic or distress, and has a great sense of duty,

is staunchly loyal, firm, and unbending in her beliefs. She is a hard worker and takes a strong moral stance — she particularly believes in following orders. She is generally reserved and truly not arrogant in any manner like her lieutenant, though she is not above mocking/joking around with her opponents or smirking while in combat

Rukia retains her modesty, even as an adopted member of the nobility. is very good at acting, having acted her way through a number of tough situations, such as getting out of trouble with school teacher

Byakuya looks immutably solemn; as befits his status, he always acts and speaks in a dignified manner. He appears inflexibly stoic as well as apathetic towards everyone, even when actually deeply conflicted. He generally acts indifferent, bordering on arrogance, to most situations he is faced with, and rarely views his opponent as being worth his time. He is the older brother to Rukia

Shunsui is a laid-back and flamboyant man, evident in his style of dress and general attitude and is usually smiling. In his off time, he often drinks sake in bars and naps. He likes steamed buns that go with sake