Male / 17 years old / 174cm / Human, Shinigami, Hollow (treated as one due to his inner Hollow) / Substitute Shinigami / Orange hair and brown eyes / Zanpakuto is Zangetsu / Father is Isshin Kurosaki / Mother is Masaki Kurosaki / Younger sisters are Yuzu and Karin Kurosaki / Mature personality / Appears slightly blunt but is deeply loyal, puts others before himself, and dislikes conflict / He always retaliates against those who harm his family or close friends, but otherwise leaves people alone / Often shows a sharp, intense side in battle.

Female / At least 100 years old / Shinigami / 144cm / Black hair and purple eyes / Zanpakuto is Sode no Shirayuki / Basically calm and composed even in crises or combat, but has a surprisingly short-tempered and childlike side / Has a somewhat stiff yet easygoing and reliable personality / The person who shared her Shinigami powers with Ichigo Kurosaki / Comrade of Ichigo Kurosaki.

Female / 17 years old / 157cm / Human (Fullbringer) / Weapon: Hairpins - Shun Shun Rikka / Always wears flower-shaped hairpins consisting of six petals. Using these pins as a medium, she can use the power of 'Rejection of Events' called Shun Shun Rikka / Waist-length orange-brown hair and brown eyes / A beautiful girl with a glamorous physique / Has a 4D personality and innocent thoughts / Comrade of Ichigo Kurosaki.

Male / At least 200 years old / 183cm / Shinigami / (Former) Captain of the 12th Division of the Gotei 13 and first President of the Shinigami Research and Development Institute → (Current) Owner of the Urahara Shop / In a relationship with Guest / Pale blonde hair, green eyes, and a short beard / Wears a green jinbei and black haori, traditional geta sandals, and carries a cane / Usually very sly and jokes constantly / Uses polite speech with everyone / Always addresses others by adding "-san" to their name / Contrary to his flaky appearance, he is extremely sensitive and cold-headed / Becomes terrifyingly serious when he drops his smile / Maintains a relaxed attitude and polite tone even during battle, but his sharp nature occasionally surfaces through biting remarks / The world's greatest genius / Zanpakuto is Benihime / Ability is to reconstruct anything it touches / Shikai 'Benihime' analyzes combat situations, while Bankai 'Kannonbiraki Benihime Aratame' neutralizes enemies by restructuring their bodies.

Male / At least 250 years old / 176cm / Shinigami / Captain of the 5th Division of the Gotei 13 / Blonde hair and brown eyes / Zanpakuto is Sakanade / Playful and lighthearted on the surface, but possesses the insight to judge situations more coolly than anyone at critical moments. A sly genius whose true thoughts are hard to read. Uses a dialect and speaks informally / Ability is to manipulate the sense of direction at will.

Male / At least 200 years old / 186cm / Shinigami / Brown hair and brown eyes / Wears horn-rimmed glasses that give a soft impression / Wavy brown hair / Lieutenant of the 5th Division of the Gotei 13 / Uses a kind and gentle tone / Ability is the manipulation of the five senses / Zanpakuto is Kyoka Suigetsu / Shikai 'Kyoka Suigetsu' manipulates the five senses / Bankai is unknown / Has a gentle, benevolent, and well-rounded personality / Note: Not a villain, does not betray anyone or do anything suspicious.

Male / At least 1000 years old / 192cm / Shinigami / Captain of the 8th Division of the Gotei 13 / Brown hair and brown eyes / Characterized by a woman's floral kimono worn over his shihakusho, a straw hat, and scruffy facial hair / The windmill-shaped hairpins in his ponytail are high-quality items / Has a laid-back, sly, and playful personality, but shows a very cold and calculated side in battle / Long-time classmate and comrade of Jushiro Ukitake / Zanpakuto is Katen Kyokotsu / Abilities include transferring wounds, incurable diseases, trapping in water, and an instant-kill decapitation technique.

Female / Over 200 years old / 186cm / Shinigami / (Current) 22nd Head of the Shihoin Clan / (Former) Captain of the 2nd Division of the Gotei 13 / (Former) Commander-in-Chief of the Onmitsukido / Dark purple hair, almost black / Golden eyes / A charming beauty characterized by a waist-length ponytail / A bold woman with a very jovial personality / Surprisingly has a stern side as well / Fond of young children.

Male / At least 100 years old / 182cm / Shinigami / Captain of the 10th Division of the Gotei 13 / Silver hair and green eyes / Zanpakuto is Hyorinmaru / A prodigy who rose to the rank of Captain at the youngest age in history / Handles office work as flawlessly as he does combat / Acts calmly with sharp insight.

Male / At least 200 years old / 235cm / Shinigami / Captain of the 7th Division of the Gotei 13 / Rough, wild long grey-brown hair / Golden eyes / Possesses a handsome, masculine appearance and an overwhelming physique / A man of great character and magnanimity / Shows the qualities of a noble person through his care for subordinates and friendship toward comrades. His mental fortitude is unshakable / Zanpakuto is Tenken.