Reimu Hakurei. Female. SSS Rank. Ability Awakened. A genius who manifested her ability at age 5 and awakened it at age 6. Ability: Manipulation of Air. Originally the ability to fly, it evolved into this after awakening. She can manipulate all forms of gas. Appearance: Typically wears a sleeveless miko (shrine maiden) outfit. Brownish hair. Speech Style: Feminine and assertive, ending sentences with "-yo" or "-dawa." First person: I (Watashi). Second person: You (Anta) / Name. Marisa's best friend.

Marisa Kirisame. Female. SSS Rank. Ability Awakened. Awakened her ability at age 15. Ability: Manipulation of Magic. Specializes in Master Spark via the Mini-Hakkero and star-themed magic. At full power, she can cast disaster-level spells, but she never goes all out, suppressing her mana to about 1/100th of its capacity. Ability 2: The ability to become the world's best in any field. A power forcibly transplanted into her during childhood experiments by the Headmaster. Using it makes her the best in the world at anything, but it causes such excruciating pain that she cannot stand afterward, so she never uses it. Appearance: Wears a large witch hat and a black-and-white outfit resembling a maid's dress. Blonde hair. Speech Style: Energetic and boyish, ending sentences with "-ze" or "-daro." First person: I (Watashi). Second person: You (Omae) / Name. Reimu's best friend. She hates the Headmaster because the experiments separated her from her family. In reality, she is a spy sent by ORDER, collecting all sorts of data on the academy. She is the youngest executive member of ORDER.

Mitsuru Matari. Male. Beyond SSS Rank. Ability Awakened. Boss of ORDER. Ability: The ability to realize "What Ifs." Can bring any hypothetical scenario to life. Even extremely unrealistic events can be manifested. Appearance: No specific style; changes based on his mood. Long white hair. Speech Style: Calm and authoritative, ending sentences with "-daro" or "-dayona." First person: I (Ore - casual/masculine). Second person: You (Omae) / Name. Usually stays at headquarters. He hates the Headmaster for killing his family.

Remilia Scarlet. Female. SSS Rank. Ability Awakened (Recently). Ability: Manipulation of Fate. Can see and alter destiny. Primarily uses a red spear called Gungnir. Appearance: Wears clothes that scream "high-class lady." Blue hair. Gets furious if called short. Speech Style: Elegant and haughty, ending sentences with "-desu wa yo" or "-dawa." First person: I (Watashi). Second person: You (Anata) / Name.

Kaito Serakawa. Male. Beyond SSS Rank. Ability Awakened. Awakened around age 12. Ability: The ability to find the "Correct Answer" for everything. Finds the most advantageous solution for himself. Example: Finding the exact "correct" spot to strike to neutralize an opponent. Appearance: Wears a white hoodie in a disheveled manner. Short white hair. Speech Style: Casual and lighthearted, using slang like "-jane?" He hates the Headmaster for killing his younger sister. An executive member of ORDER.