Punie Tanaka The Princess of the Holy Magical Kingdom. She transfers to a school on Earth for her training. She appears to be a cute, energetic girl who uses her Miracle Rod to make everyone happy with magic, but that is merely a facade. Her true nature is cold and ruthless, looking down on all creation with eyes like ice. She is a mischievous girl who is actually better at submission holds than magic. She is completely hopeless at studying. Magic Chant: "Lyrical Tokarev, Kill Them All." When using submission holds, she says things like "Striking techniques are just flashy showmanship! Submission holds are the true techniques of a champion!"

Tetsuko Kuni President of the Railway Research Club. A kind-hearted girl. She becomes close friends with Punie after a commotion at a curry stall during the school festival. A moe-style glasses girl who loves trains from the bottom of her heart. She is well-endowed and has a motherly, caring nature.

The sukeban (delinquent leader) who rules the school Punie transferred to. She finds Punie's act of acting cute to captivate the male students eyesores, so she brings her lackeys to try and teach Punie a lesson... By the way, she's actually quite cute.

The daughter of King Barbarock, the legitimate ruler of the Holy Magical Kingdom. She was ousted from the throne by the schemes of Punie's mother (Esmeralda) and seeks revenge. Because she often tries to trap Punie in pitfalls, she is called "Ditch-digger Elise" (which she hates). On Earth, she attends the same class in the same high school as Punie, but lives in poverty; Elise paints figures while her mother makes artificial flowers as side jobs to make ends meet. Magic Chant: "Tekeretsu no Pa."

Punie's twin sister. She has a foul mouth (especially towards Anego) and still talks like a baby. Despite being a young child, she tries to kill Punie using large scissors. She has black hair. She appears occasionally.

Punie's twin sister. She has a foul mouth (especially towards Anego) and still talks like a baby. Despite being a young child, she tries to kill Punie using large scissors. She has blonde hair. She appears occasionally.

Punie's mascot animal. He became Punie's mascot after a fight to the death in the Waku Waku Mascot Village. Although he has an adorable appearance, he has a past as Colonel Paya Livingston, having fought through numerous battlefields. Even now, he is the closest assassin, seeking Punie's life whenever he finds an opening.