Female. Elf. Mage. 150cm. Has lived for over 1,000 years. She has silver hair and green eyes. Her hairstyle is almost always twin tails, except for scenes where she has just woken up. As an elf, she has pointed ears and wears red earrings, with somewhat sharp eyes and rounded eyebrows. She usually wears white-toned clothing. She maintains an appearance that looks like a human in her mid-teens. A detached, expressionless face is her default look. This can sometimes be misunderstood as indifference, but she is actually quite kind-hearted. Being an elf with an infinite lifespan, her sense of time differs from that of humans. A "brief stay" for her lasts at least 6 years, and on average over 10 years. She is serious about collecting useless, trivial magic. Whenever she sees a treasure chest in a dungeon, she insists on opening it, but most are Mimics and she ends up half-swallowed. She seeks to kill demons on sight. She hates being called an old lady and dislikes being treated like a child.

Female. Human. Mage. 162cm. First-Class Mage. A girl with long purple hair, purple eyes, and a calm gaze. She wears a black mage robe and carries the staff she received from Heiter. Having been raised by the priest Heiter, she is fundamentally devout and warm-hearted, and she uses polite speech with others. However, despite her polite tone, she says everything that needs to be said; she relentlessly nags her master Frieren, who often appears slovenly, speaks bluntly to the troublemaker Stark, and delivers sharp-tongued remarks whenever Sein acts like a corrupt priest. She has a practical personality and acts as the mother figure of the party, taking care of the members and managing their livelihood. Yet, she also has a girlish side appropriate for her age, liking sweets and showing interest in accessories. Both Frieren and Serie have declared that in terms of talent, she possesses the potential to eventually surpass even Serie, the pinnacle of mages. Usually, she uses nothing but Zoltraak, which is Frieren's influence. She has a romantic spark with Stark.

Male. Human. Warrior. A young man with red hair that is black at the roots, and a large scar covering his left forehead and eye area. Due to his sanpaku eyes and the scar, he is said to look strong. Though he has a slender build for a warrior, he possesses incredible superhuman strength that belies his appearance. He uses a battle axe. He is from a village of warriors and is the top disciple of the warrior Eisen, but in reality, he is a huge coward. However, he has a persistent side that allows him to suppress his timidity to help people in danger. He is fundamentally a klutz with a fragile heart, and being shot down by Fern's sharp tongue is a daily occurrence. Usually, he is the one to back down, but occasionally he gets hurt by Fern's excessive words and runs away. He has a romantic spark with Fern.

Male. Human. Priest. A human with a brown ponytail, a goatee, and green eyes. A priest who is so debauched he could be called corrupt, with a love for gambling, alcohol, tobacco, and sexy older women. Because of this, he is usually seen as unreliable by the party, but he is quite deep and has excellent insight, so he listens to the party's concerns. In crisis situations, his usual playful attitude vanishes, and he shows a serious demeanor, acting as a priest should. His skill in holy magic is exceptional. Furthermore, while priests are essentially removed from combat, Sein possesses enough combat ability to protect himself, making good use of his sturdy physique. He uses informal speech.

Female. Elf. Mage. An elf with long yellow hair and golden eyes. Due to her arrogant attitude, cold and cynical way of speaking, and the typical elven lack of emotional expression, she may seem heartless at first glance, but she is actually deep-hearted, much like Frieren. She is the head of the Continental Magic Association.

Female. Human. Mage. Light brown hair long enough to almost touch the floor, and purple eyes. She lacks facial expressions and has a stern tone. However, among the First-Class Mages, she is a moderate pacifist. She is a First-Class Mage belonging to the Continental Magic Association.

Female. Human. Mage. A human with green hair in a right-side-up ponytail, half-closed eyes, and a Goth-look fashion. A sly and cheerful battle maniac with distorted senses and emotions unlike ordinary people, and a sadistic thrill-killer. However, she is by no means a vile criminal who goes around committing random murders. First-Class Mage.

Female. Human. Mage. A human with brown hair and purple eyes. Contrary to her cool impression, she has a personality that loves small and cute things. Still, she is quite normal among the First-Class Mages. First-Class Mage.

Male. Human. Mage. An elderly man with brown hair, a long beard, and a monocle on his left eye. Despite his intimidating career, he has a warm heart, not minding when commoners act rudely and treating young children with kindness. First-Class Mage.

Male. Human. Mage. A human with a sharp impression and glasses. He has an unsociable personality and keeps his distance because he cannot trust others, but he cannot tolerate others dying because of him. First-Class Mage.