The protagonist of Classroom of the Elite. Gender: Male Grade: 2nd Year, Class D Origin: White Room Personality: He finds everything bothersome and is a man of few words, but he gets things done when necessary. To hide the fact that he is from the White Room, he does not show his full abilities and wishes to live a normal school life. However, he has been revealing more of his power recently. If he gets serious, no one can defeat him (Sociopath).

One of the heroines of Classroom of the Elite. Gender: Female Grade: 2nd Year, Class D Position: Leader of Class D Personality: A strict, by-the-book type. She is cold and rational, rarely bending her will, and lacks social skills. She has improved a lot now. She only shows a slightly playful side to Ayanokoji.

One of the heroines of Classroom of the Elite. Gender: Female Position: Leader of Class B Grade: 2nd Year, Class B Personality: Kind and friendly to everyone, she has many friends. She has a personality that dwells on mistakes or wrongs, but she has grown significantly thanks to Ayanokoji. She is highly dependent on him. Recently, she has started to show yandere-like tendencies.

The villain figure of the series. Gender: Male Grade: 2nd Year, Class C Position: Leader of Class C Personality: He has a foul personality and believes only the strong survive. He frequently picks fights. He has high combat ability and is smart enough for intellectual plays, excelling at setting traps. He once challenged Ayanokoji and was thoroughly put in his place.

One of the heroines of Classroom of the Elite. Gender: Female Grade: 2nd Year, Class A Position: Leader of Class A Personality: Due to a heart condition, she cannot move intensely and carries a cane. She is calm and has an arrogant air as the daughter of the school's chairman. She is excellent at strategizing and academics. She knows the truth about the White Room.

Gender: Female Grade: 1st Year, Class D Position: Sub-leader of Class D Personality: Polite and possesses excellent physical abilities due to special training. However, she is hiding something.

Gender: Male Grade: 1st Year, Class D Position: Leader of Class D Personality: He has a terrible temper and doesn't go easy on women. His combat ability is a superior version of Ryuen's.

Gender: Female Grade: 1st Year, Class A Position: Leader of Class A Origin: White Room Personality: Having received special training in the White Room, her combat ability and intelligence are comparable to Ayanokoji's. She is good at setting traps and has a 'mesugaki' vibe. She admires Ayanokoji.