Appearance: An elf girl characterized by white twin-tails, green eyes, and long ears. Though she has a small, youthful appearance, she carries a calm atmosphere from living over 1,000 years. Magic: Known as "Frieren the Slayer," the mage who has killed the most demons in history. She possesses an overwhelming amount of mana, which she usually conceals to the extreme. Rather than flashy magic, she prefers "Ordinary Offensive Magic (Zoltraak)" for killing demons and collecting "silly spells" for daily life. Personality: Lazy and a late riser, she appears cold and emotionally detached at first glance. However, she is kind at heart and is continuing her journey to understand the human "heart" and deepen her connection to the hero Himmel, who she once traveled with.

Appearance: A human girl with a gentle atmosphere, characterized by long, rich purple hair and a rounded face. During their journey, she surpassed Frieren in height and now has a more mature physique. Magic: A genius who received elite education from Frieren and passed the First-Class Mage Exam at a young age. Her "detection" and "casting speed" are unnaturally fast, and she overwhelms powerful foes using only basic "Ordinary Offensive Magic (Zoltraak)" and defensive spells. Personality: A serious, hardworking, and caring person. She acts as a surrogate "mother" to the lazy Frieren, supporting her daily life. While she is not good at expressing emotions, she has a childish side where she visibly pouts when displeased.

Appearance: A petite woman characterized by incredibly voluminous black hair that reaches her feet (light brown in the anime) and bangs that almost entirely hide her eyes. Though she looks as young as a girl, her age is unknown. Magic: She uses magic to freely manipulate her own hair. Her hair, imbued with multiple layers of powerful defensive spells, possesses enough hardness and offensive power to easily slice through human bodies or giant stone pillars, making her peerless in close-quarters combat. Personality: A self-proclaimed "pacifist." Quiet and expressionless with a harsh tone, she also shows kindness by providing escape golems to ensure examinees' lives aren't wasted. However, she is famous as a ruthless proctor; in the past, every exam she oversaw resulted in zero passing candidates.

Appearance: An elf in the form of a petite girl with long golden hair and the long ears characteristic of her race. Though she looks even smaller and younger than Frieren, she radiates overwhelming pressure and majesty, having lived since the age of myth. Magic: A "living grimoire" who encompasses almost every spell in human history. She was the master of Frieren's master, Flamme, and possesses the greatest mana capacity in the world. She has the intuition to see through an examinee's talent and grants those she recognizes as First-Class Mages the privilege of receiving "one spell they desire." Personality: An arrogant and cold meritocrat. She views magic as "power" and rejects Frieren's hobby of collecting spells. However, despite her dismissive words, she secretly remembers the favorite spells and preferences of all her past disciples, including Flamme, showing a deeply compassionate side.

Appearance: A beautiful, mature woman characterized by wavy, glossy blonde hair, blue eyes, and a stunning figure. She is notably tall among the major female mages in the series, exuding the aura of an elegant older sister. Magic: Hailing from a clan specialized in demon hunting, she is a versatile all-rounder covering not just offense and defense, but also binding, mental manipulation, mana detection, and even rare "Healing Magic (Goddess Magic)." Personality: Always rational and intelligent, she is a calm and reliable older sister figure skilled at situational analysis. However, she hides a fierce nature dedicated to spending her life killing demons. She also has a severe obsession with "small and cute things," showing a comical and intense side where she tries to hug and pet Frieren or Serie whenever she gets the chance.

Appearance: A dignified elderly mage with a stern face, a magnificent white beard, and short white hair. He exudes the prestige of a court mage and wears high-quality clothing. Magic: A winner of power struggles who manipulates an overwhelming variety of spells and robust defensive magic backed by vast combat experience. In the First-Class Exam, after his mana was exhausted, he showed a strong obsession with victory and high combat IQ by opening a path forward through a gritty fistfight. Personality: While he appears to be a cunning and power-hungry politician, he is actually a hot-blooded man who is compassionate and loyal. He is well-liked by other examinees for his tendency to look after younger mages. His pure motivation for becoming a First-Class Mage is to visit his late wife's grave in his hometown.

Magic: Her signature is "Magic to Cleave Anything (Reilseifen)." Anything she intuitively feels she "can cut" will be sliced through, even defensive magic or reinforced cloaks. She also has a genius talent for making others' magic her own through empathy. Appearance: A girl with a green side-tail and enchanting, somewhat vacant sanpaku eyes. She wears a revealing black outfit with strings, exuding a mysterious sex appeal despite her small stature. Personality: She has a cunning and battle-crazed side, with psychopathic tendencies showing a strong interest in others' emotions. However, she possesses a unique emotional depth, placing great importance on "empathizing" deeply with others.

A golem created to facilitate escape from the dungeon. If you break the bottle, it will carry you outside the dungeon.