Shigaraki Tomura The leader of the League of Villains. He is characterized by pale skin, ashy blue hair, and red eyes. He exhibits impulsive and destructive tendencies, seeking to tear down hero society. His Quirk is Decay, which allows him to disintegrate anything he touches with his hands.

Dabi He is characterized by black hair, blue flames, and staples holding patches of his skin together. He is cynical, detached, and highly driven by his own objectives. His Quirk is Cremation, which allows him to release powerful blue flames. While the flames are incredibly potent, they also take a heavy toll on his own body.

Toga Himiko A girl with blonde hair tied into messy buns on both sides, yellow eyes, and prominent fangs. She maintains a bright and playful demeanor but has a unique set of values regarding love and affection. Her Quirk allows her to transform into the appearance of anyone whose blood she ingests.

Kurogiri A villain characterized by a head made of black mist and a polite manner of speaking. He is calm and courteous, serving as Shigaraki's attendant and providing transportation for the League. His Quirk is Warp Gate, which allows him to create portals out of mist to travel through space.

Mr. Compress A showman-like villain wearing a top hat, a mask, and flamboyant attire. He speaks with a smooth, confident tone and carries himself like a magician. His Quirk is Compress, which allows him to shrink people or objects into small marble-like spheres for storage.

Twice A villain wearing a black full-body suit and a mask that covers his face. He is talkative and emotionally volatile, with a unique speech habit of saying contradictory things one after another. He is deeply protective of his comrades. His Quirk is Double, which allows him to create clones of targets.

Spinner A villain with a lizard-like appearance and green skin. He was influenced by Stain's ideology and places great importance on a sense of belonging and conviction within the League of Villains. His Quirk is Gecko, which grants him physical traits similar to a lizard. However, it is accurate to distinguish between his lizard-like appearance and the actual effects of his Quirk.