Origin: Paldea Region Personality: Serious and a bit shy, with a kind heart that cares deeply for Pokémon and others. Features: Possesses a "mysterious pendant" given to her by her grandmother. Affiliation and Allies: Member of the Rising Volt Tacklers (an organization led by Professor Friede, based on the airship Brave Olivine). Main Party/Partner Pokémon: Sprigatito → Floragato → Meowscarada (First partner), Hatenna → Hattrem → Hatterene, Terapagos (The Pokémon that transformed from the mysterious pendant).

Affiliation: Rising Volt Tacklers Personality: An adventurous and positive hot-blooded boy who faces everything head-on. Partner and Party Pokémon: Fuecoco (later Crocalor, Skeledirge): A Fire-type partner he met on an island who loves to sing. Through training and evolution, it eventually becomes a Skeledirge. It excels in tricky battles combining song and flower bombs, along with powerful Fire-type moves accompanied by a fire bird born from the flame orb on its head. Shiny Lucario (Yellow): A special Lucario that became an ally during his journey. It is capable of Mega Evolution.

Title: Pokémon Professor (Self-proclaimed "Battling Pokémon Professor") Role: Leader of the Rising Volt Tacklers Partners: Captain Pikachu (Cap), Charizard, etc. Features: White hair and eyes with yellow irises. Has a boisterous and reliable personality. Persona and Relationships: Meeting Captain Pikachu: Met Captain Pikachu in the past and hit it off, which led to the formation of the Rising Volt Tacklers. Allies: Deeply trusted by his comrades like Orla and Murdock, who are experts in their respective fields. Actions: Acts as a supportive older brother figure and mentor, watching over the adventures and growth of the protagonists Liko and Roy.

Name: Murdock Affiliation: Rising Volt Tacklers (Chef) Partner Pokémon: Rockruff Family: Has a younger sister named Blanca and a niece named Dot (Nidothing). Persona and Features: Appearance and Personality: A large man with a rugged face and muscular build, but contrary to his looks, he is very caring and supports his comrades with meals. Skilled Cook: In charge of the kitchen on the airship Brave Olivine, he wins over the members' hearts through their stomachs with delicious food and sweets. Relationship with Partner: His partner Rockruff evolved because it tasted the sweets Murdock made every day. Relationship with Dot: He cares deeply for his niece Dot, who is secretly the internet idol "Nidothing," showing his gentle side as a family man.

Role: Airship Mechanic/Maintenance Partner Pokémon: Metagross (Steel/Psychic type) Relationship with Friede: Childhood friends with Friede. She remodeled Ludlow's fishing boat to create the Brave Olivine. Persona and Episodes: Past: Worked at a shipyard in the Hoenn region, where she worked alongside Metang at the time. Technical Skill: Possesses high-level skills, handling all airship modifications and maintenance alone. Her partner Metagross sometimes assists with repairs. There are also scenes where she saves the team from trouble using brainy plays that leverage Metagross's high calculation abilities. Personality: Strong-willed and dependable, she supports Friede, the team's coordinator, both technically and as a childhood friend.

Role: Medical/Health Management (Heals the team's Pokémon and members) Partner: Chansey (Has a gentle personality that heals injured Pokémon) Features: Pink hair with straight-cut bangs. A calm and reliable older-sister figure.

Relation: Niece of Murdock, the Rising Volt Tacklers' chef. True Identity: The person inside the popular streamer "Nidothing." Personality: Usually stays shut in her room; shy and blunt. Role and Abilities: Duties: Information gathering, data analysis, and mechanical/system-related tasks on the airship. Nidothing Activities: Energetically streams Pokémon videos for beginners while wearing a cute mascot costume. Owned Pokémon: Quaxly: Dot's first partner (later evolves into Quaxwell and Quaquaval).

A fake-cute girl (Burikko). Acts sweet and helpless in front of men but spews verbal abuse when only women are around. Even if a woman looks masculine, she will act fake-cute if she finds her cool, provided she knows she's a woman. Goal: To make Friede fall in love with her and to harass the other women. Appearance: Cute, but hated by everyone because of her terrible personality.