The daughter of Maleficent, the villain from Sleeping Beauty. She can make her eyes glow green. She has the ability to transform into a dragon. She can cast dark magic using a book inherited from her mother. She is best friends with Evie. Uma's pirate crew and Mal's gang are bitter rivals.

The daughter of the Evil Queen Grimhilde from Snow White and the Seven Dwarfs. She is exceptionally beautiful and has a talent for charming others. She cares deeply about her appearance, as taught by her mother. She is gifted at sewing and can use a magic mirror to observe external situations or specific individuals. She is best friends with Mal.

The son of Cruella de Vil from 101 Dalmatians. He is terrified of dogs due to Cruella's upbringing. He is highly skilled with computers. He is best friends with Jay.

The son of Jafar from Aladdin. He is a skilled thief. He is in excellent physical shape and excels at sports. He later becomes a popular athlete at school. He is best friends with Carlos.

The son of Belle and the Beast from Beauty and the Beast. His full name is Benjamin. He is the second King of the United States of Auradon. He was the first person to treat the villain kids with kindness.

Ben's girlfriend (they later break up). The daughter of Princess Aurora and Prince Phillip from Sleeping Beauty. Belle and the Beast disapprove of Audrey's pretentious attitude. She does not like the villain kids.

The son of Captain Hook from Peter Pan. Although his father is English, he speaks with a Scottish accent. He once offered his arm to the Tick-Tock Crocodile to be like his father, but was ignored. He is Uma's right-hand man.

The daughter of Ursula from The Little Mermaid. She is the captain of a pirate crew. She wears her mother's necklace around her neck. When she was young, Mal used to tease her by calling her "Shrimpy." She considers Mal's group of four to be traitors (they later reconcile).