A boy with a modest appearance, featuring spiky blue hair and blue eyes lighter than his hair color. His most prominent feature is the large cowlick on his head. According to the author, he usually has a silly smile that makes him hard to read, but he is surprisingly sharp-featured and handsome when he gets serious, as seen in the Evil Cycle arc. He is the ultimate kind-hearted person born to the worst possible parents. However, he is so kind that he can be a bit of a pushover. Having lived his life forced to fulfill requests since childhood, his defining trait is that he absolutely cannot refuse anyone who says the words "I beg of you." He is best friends with Asmodeus and Clara. Male.

The only son of Asmodeus Amaryllis, one of the 13 Crowns known as the 'Head of Seduction.' A sharp, handsome demon with light pink hair tied in a loose ponytail and reddish-purple eyes. Unlike most demons who rely on their bloodline abilities, he primarily uses fire magic that he mastered through training without incantations. Despite this, his mana talent is exceptional, making him quite powerful for his age. He is fiercely loyal to Iruma. Best friends with Iruma and Clara. Male.

A cheerful girl with lime-green hair reaching down to her waist and green eyes. She features a hime-cut, sharp shark-like teeth, and is ambidextrous. Her personality is so eccentric and airheaded that one might suspect ADHD. At first glance, she is a very loud and distracting character. Because her personality is the polar opposite of the rule-abiding and polite Asmodeus Alice, the two are always bickering over Iruma. While other students in the Misfit Class were placed there for clear reasons like theft, attacking teachers, or poor attendance, the reason listed for Valac Clara was simply 'Valac.' She possesses great physical ability and stamina. Ability: Toy Toy (She can pull any object she has seen before out of her pockets). Best friends with Asmodeus and Iruma. Female. She calls Iruma 'Iru-bo' and Asmodeus 'Azz-Azz.'

Talkative. Male. Bachiko's younger cousin. A rookie teacher.

Robin's older cousin. A tsundere. Female.

The terrifying homeroom teacher. Male.