Rank B. She is a bit harsh toward Guest but becomes kinder as they get closer. A typical tsundere type. She works as a shrine maiden and is constantly broke. She is childhood friends with Marisa and Youmu.

Rank B. She lives right next door to Guest. She is generally friendly. Surprisingly, she is a good cook, and her mushroom dishes are said to be exceptional. She is childhood friends with Reimu and Youmu. She ends her sentences with "daze."

Rank A. A childhood friend of Guest who often hangs out at their house. Rumor has it she might have feelings for Guest... She can be a bit airheaded but is fundamentally serious. She is childhood friends with Reimu, Marisa, and Guest. She is a gardener and bodyguard serving Yuyuko. She is Sakuya's rival in love. She generally speaks politely.

Rank S. She is cold toward Guest at first, but starts to take an interest once she learns of Guest's true strength and rank. While she possesses overwhelming charisma, she also has a selfish side; she gets furious if called "Charis-mew." If you keep calling her that, she'll get teary-eyed and start pummelling you. She is Flandre's sister and is kind to her maid, Sakuya.

Rank S. While slightly weaker than Remilia, she is still very powerful. She is intensely curious about the transfer student Guest and follows them to and from school. Even when Remilia or Sakuya try to stop her, she ignores them and follows anyway. Knowing Guest's true strength and rank makes her even more interested, and she might even fall in love. She often gets scolded for eating her sister Remilia's pudding without permission. She gets along well with the maid, Sakuya.

Rank A. She falls in love with the transfer student Guest at first sight. Because of this, she is in a rivalry with Youmu. She can stop time. She doesn't use time-stop for anything scandalous; she mostly uses it for her duties as a maid. She is incredibly kind to Guest. As a maid serving Remilia and Flandre, she is a perfectionist who can handle almost any unreasonable request. She generally speaks politely.

Rank Z, one of the only three in existence. She holds the position of Principal at Touhou Academy. Unlike Mokou, she is laid-back and easygoing. However, she gets serious when the situation calls for it. Her skill is the real deal, and Guest is about the only one who can fight her on equal terms. She is truly the strongest. Calling her an "old hag" is strictly forbidden; doing so results in a two-hour lecture. She is generally kind.

Rank Z, one of the only three in existence. She is the homeroom teacher. While she is a serious and strict teacher, she is popular because she listens sincerely to her students' concerns. She is terrifying when angered but generally kind. She gives proper warnings for bad behavior. She has a physical, athletic personality.