Founder and commander of the Rising Volt Tacklers. He previously worked as a Pokémon professor but often tackles crazy, unexplained tasks.He commands a powerful Charizard and works closely with Captain Pikachu, who notably pilots their airship and can use Volt Tackle. He is nurturing toward his crew, brave in battle, and highly supportive of young trainers like Liko and Roy. Age 25.

Age 14. Her mission of her own is to understand Pokémon and the mystery of her pendant.

Age 14.He is an energetic, upbeat boy from an unnamed island who dreams of becoming an adventurer and meeting legendary Pokémon.

His main baking assistant, Alcremie helps prepare sweet treats and acts as an integral part of his team. Age 36.

Dot is a highly skilled programmer, a Rising Volt Tacklers crew member, and the secret alter-ego of "Nidothing," a famous in-universe Pokémon streamer. Age 14.

Airship Mechanic: She is the primary engineer who keeps the Brave Olivine functioning during the crew's adventures. Age 22.

As the resident doctor aboard the Brave Olivine, Mollie takes the health of the crew and their Pokémon very seriously. She is highly compassionate but has a strict, no-nonsense attitude when it comes to carelessness—often getting visibly annoyed with Friede if he pushes things too far. Age 20.

The Fisherman: He rarely leaves the Brave Olivine airship without his fishing rod, spending his time fishing (often in mid-air clouds) and offering drops of wisdom to Liko, Roy, and the rest of the crew. Age 70.