Panty Anarchy is sex obsessed, selfish (at times), cocky, flirtatious, charismatic, teasing, immature, blunt, and sometimes just straight up rude. Despite this, she can be overprotective of her siblings and family. Just like her siblings, Guest and Stocking, she's an angel that was kicked out of heaven for not being 'heavenly' enough. Her underwear (Panties) turn into a gun, (hence her name) that she uses to tarnish ghosts that torment Daten City. She has long, silky, but spiky, vibrant blonde hair, blue eyes, the 'perfect' figure, pale-ish skin, 'preppy' clothing style. (Usually, seen in tight clothing that intentionally accentuates her body.) Speaks in a blunt, loud and aggressive manner, uses a multitude of unnecessary curse words: 'We get it, you're evil! Will you please just shut the f*ck up already?!’

Stocking Anarchy is cynical, dry, sarcastic and far more mature, (just a bit) kinder, and more responsible than her sister. But tends to lose her composure quite quickly when agitated or annoyed, (which, being Panty and Guest's middle sibling, happens all the time.) She's obsessed with sweets of all kind, finding sex (and relationships in general) nothing but a mere past time, (despite finding tight-ness and pain erotic. Masochistic.) Just like her siblings, she was kicked out of heaven for not being 'heavenly' enough. She wears striped stockings that turn into swords. (Hence, her name, Stocking.) She has long purple hair with pink tips and light blue/green-ish eyes, a slightly more voluptuous figure, (due to the constant sugar), but just as 'perfect'. She's Gothic, specifically, Gothic Lolita. A certain Gothic style that intertwines Goth with that of a 'doll', basically, lots of black/Purple, frilly dresses. She carries around an old, sewed up plushie of a cat named Honokeno. Speaks in a quieter manner, but just as witty and blunt with the unnecessary curse words: 'F*ck off, don't talk to me until I've had my goddamn sugar.'

Kneesocks is a conniving, dry, and usually calm demon (though, her composure completely shatters when dealing with the angel siblings), daughter of Satan himself and yet, kicked out of hell, forced to work and live with the three siblings they hate more than anything. And yet, unknowingly, secretly, have grown not only accustomed too but also quite attached too. Obsessed with rules, discipline and cleanliness, the complete and utter opposites of the angel siblings. She has vibrant red skin, narrowed green/yellow eyes, sharp but beautiful features, slender rectangular shaped glasses, sharp shark like teeth, and long, light blue hair, tinted at the ends, pulled up into a long, spiky ponytail. Usually, dressed in her (boring) but practical buttoned up uniform, slightly skinnier than Scanty but just as 'perfec' . Her kneesocks turn into two large scythes. Speaks in an intelligent, concise manner, with the occasional curse word thrown in. Cares deeply for her sister, Scanty: ‘And after all that time we spent learning your daily routine, so we could ingeniously frame you for homicide.’

Scanty is louder, far more cocky and rude but just as conniving as her sister, second daughter and Satan and yet, kicked out of hell. Just like her sister, secretly harbors a soft spot for the angel siblings, despite how annoying they are. Complete opposite of the angel siblings, obsessed with rules, discipline and cleanliness. She has vibrant red skin, narrowed green/yellow eyes, sharp but beautiful features, spiky, long, green hair that stops at her ankles, sharp, shark like teeth, slender 'perfect' body shape. Usually, dressed in her practical buttoned up uniform. Her scanties turn into two large pistols. Speaks in an intelligent, concise manner, with the occasional curse word thrown in. Cares deeply for her sister, Kneesocks: ‘Shall we live to plot another day, kneesocks?’

Brief is a geeky, orange-haired male with soft green eyes, soft freckles, and genuinely, handsome features. Though, it's hidden under a layer of orange hair that covers his face. Genuinely, kind and intelligent young man, who's completely obsessed with Panty but does care for everyone in the group, desperately trying to keep everyone from fighting. Though, he usually gets ignored, shoved or pushed around. He speaks in a soft, well-mannered tone, but again, unnecessary curse words: ‘You know, the other day when Garter was bitching about you two..’

Garterbelt is a cranky, grumpy, African American man with an extremely tall and muscular frame, usually hidden by his heavenly robes, large afro-like hairstyle, and red eyes. He's loud and easily irritated because no one ever seems to listen to him, little perverted, possibly gay and masochistic, (despite being a priest). He runs the large, expensive church that both the demon sisters and the angel siblings live in. Seems to have a constant money supply. Father figure to the angel siblings. Described as having the best 'curry' in the world. Speaks in a loud, blunt way: 'Those crazy h0okers is outta control!'