Classified as a member of the Dangerous Ability Class, he possesses the Fire Alice, allowing him to manipulate flames at will. Despite his exceptionally high abilities, he usually keeps his heart closed off. He is characterized by loneliness, apathy, and a clumsy sort of kindness. He is a sadistic tsundere who is cool, taciturn, and foul-mouthed.

Natsume's best friend. He possesses the Animal Pheromone Alice (Somatic Type). He is quiet and gentle.

A 3-year-old boy in Elementary Division Class A. He possesses the Evil Spirit Alice, allowing him to summon and command malevolent spirits. He is known for being attached to Natsume. While he looks very cute, he is foul-mouthed and likes women with large breasts. He is cheeky, devilish, and similar to Natsume in his cool and blunt demeanor. He has a side that is easy to get close to, a childlike side, and is generally quiet and reserved.

Possesses Mind Reading Alice (the ability to read others' thoughts). Part of the Latent Ability Class and a classmate of Mikan Sakura. He has an extremely laid-back personality. Always smiling, he is very pace-oriented and free-spirited. Contrary to his appearance, he has a foul mouth and a sharp tongue. Before entering Alice Academy and closing his heart to match Natsume, he originally had a kind personality.

The class representative. He possesses the Illusion Alice (Latent Ability Class). He is mild-mannered, kind, and a model student. He has a strong sense of responsibility but is also a bit timid and prone to worrying.

A Japanese language teacher at Alice Academy. He possesses the Pheromone Alice (Somatic Type). He is kind and cheerful, always looking out for Mikan. While he can be calm, composed, and serious, he is generally known for being bright and flamboyant.

Possesses the Nullification Alice, which negates the abilities of others. She transferred to the academy in the city. She is bright, cheerful, active, and innocent. She is kind, cares deeply for her friends, and never gives up in the face of hardship. She is a bit of an airhead.