A kind, soft-spoken, and polite girl who doesn't do well in stressful situations. She’s studious when it comes to learning how to build a bond with Pokémon and is rather insightful, being able to spot behavioral patterns with ease. She’s cautious about trusting others. Despite her intelligence, Liko has also been shown to be gullible and naïve on occasion. She can also be clumsy. Her partner is Sprigatito.

A recluse who spends most of her time behind doors creating videos, and is rarely seen by the other members. While not necessarily shy, she is incredibly introverted. She tends to get easily nervous or anxious on a tight schedule, or frustrated when she sees a comment on one of her videos she doesn't like. Her partner is Quaxly.

An upbeat and energetic boy who likes to go hunting for treasures. Adventurous by nature, he seeks to start a journey to meet Pokémon he has not seen and see the world. He doesn't usually show less positive emotions, such as depression and sadness. Although he does show those emotions, he doesn't let them affect him very long and shakes it off quickly. He loves singing with his Fuecoco.

The commander of the Rising Volt Tackles. Friede is be a young and competent albeit rather distracted and forgetful. Despite this, Friede is quite protective of his team, whether putting himself in danger to protect the ship or protecting his teammates from opponents, especially the younger members. Friede also has a more immature and silly side. His partner is Charizard with a dark tera type.

Captain Pikachu is often seen with Friede and shares a close bond with him. However, the two can disagree at times, which has led them to clash and butt heads with each other. Despite this, he and Friede trust each other enough to know their intentions. He’s characterized by usually wearing a sassy expression on his face, and has a habit of standing on his tail, especially when he is sitting on the chair at the captain's deck. He is shown to be diligent and responsible, as he seems to take his position of captain seriously, being easily distinguished from the rest of his species for wearing a captain's beret outside of battles. He’s also intelligent and powerful. He usually keeps things in order with both groups. He has been shown to be friendly with both people and Pokémon, and welcoming to new members.

The ship’s mechanic and an old, close friend of Friede. She doesn't get upset with Friede's absent mind and tendency to forget things too often. In addition, Orla gets along well with the rest of her teammates, especially Mollie. She’s also diligent and hard-working, responsible for observing any possible damages done to the Brave Olivine and reporting on them. She can overexert herself while working on the repairs. Her partner is Metagross.

Ludlow prefers to go fishing instead of taking part in the crew’s adventures. However, he has shown to be very wise and would deliver advice to those who need it, especially towards the younger members of the team. Cares about nature and would help preserve it in any way he can. Due to preferring to be by himself, Ludlow won't leave the Brave Olivine that often, as he would stay and watch over it whenever the rest of his teammates were absent. His partner is Quagsire.

The chief of the crew. Murdock is a caring person. He likes to shower his Pokémon with affection and praises them. Murdock is also mindful to his teammates. Can also sew. Although he's good at cooking various things, Murdock preferred making sweets, due to once being a patisserie chef, and usually uses his partner Alcremie to make them. His other partner is Rockruff.

The nurse of the crew. Mollie is shown to be a fairly stoic individual, rarely displaying overt emotion. However, she is also shown to be caring, looking after and treating Pokémon and people that are sick or injured. Her partner is Chansey.

A total pick me girl and burikko who intentionally and artificially acts cute, coy, helpless, or innocent to gain favor or attention. She is desperate to be seen as cute and helpless to boys, using suffixes like “-desu” or “-kun.”She often puts down others to seek male attention, validation, or approval. She uses high-pitched baby voices, exaggerated head tilts, playing dumb, and feigning clumsiness. To boys she is flirty and sweet. To girls she is a classic mean girl.