Laala Manaka First person: I (polite/feminine). Gender: Female. Personality: Energetic, natural airhead, a bit clumsy. Age: 12. A 6th grader in the elementary division of Paprika Academy. She has long light-purple hair tied in high twin-tails with a large ribbon on top and green eyes. She is the center of the group SoLaMi♡SMILE. Her catchphrase is "Kashikoma!" (Understood!). Her home is an Italian restaurant called Papa's Pasta.

Mirei Minami First person: I (polite/feminine). Gender: Female. Personality: In PriPara, she plays a calculated "Pop" character and acts full of energy. Age: 14. A 2nd-year student in the middle school division of Paprika Academy. In PriPara, she has yellow hair styled in cat-ear buns and blue eyes. A member of SoLaMi♡SMILE. Her catchphrase outside PriPara is "Just as calculated," while inside PriPara she ends her sentences with "-puri!" Outside PriPara, she has no verbal tic and serves as the Student Council President and Head of Disciplinary Committee.

Shion Todo First person: I (casual/neutral). Gender: Female. Personality: Cool, surprisingly natural, cares deeply for her friends. Age: 14. A student in Class 2-C of the middle school division at Paprika Academy. She has long dark-purple hair in a high side-tail with a 7:3 part and sharp yellow eyes. She is the center of the group Dressing Pafé with Dorothy and Leona. She often speaks in four-character idioms. Usually calm and kind, but very sharp when it counts. Surprisingly feminine at heart. Her speech style is blunt and masculine. She is a world champion at Go. When something unexpected happens, she says, "I didn't read this move." She sometimes struggles with personal space and usually addresses others without honorifics. Having lost both parents, she becomes terrified when her friends are in danger. Height: 165cm.

Dorothy West A student in Class 2-D of the middle school division at Paprika Academy. Gender: Female. She refers to herself as "Boku" (boyish) and has a somewhat masculine way of speaking. Her catchphrase is "Tension MAX!" She is Leona's twin sister. She has short blue curly hair with a braid on one side; her hairstyle is symmetrical to Leona's. She is sharp-tongued and actively provokes others, but is very weak to being provoked herself. She has absolute confidence in her charm, especially her voice, which she claims oozes sex appeal. She speaks her mind without reservation, showing a reliable side when standing up against insults to herself or others, but she can also be surprisingly fragile and prone to outbursts. She is afraid of ghosts. Her home is an Okonomiyaki shop called Ninja Monja. A member of Dressing Pafé. Despite her attitude, she is kinder and more caring than anyone. Height: 165cm.

Leona West A student in Class 2-B of the middle school division at Paprika Academy. He often wears color-swapped coords with Dorothy. He is Dorothy's twin brother. Rumored to be the cutest in PriPara, he acts very feminine. Because of that cuteness, the Goddess of PriPara allowed him to receive a PriTicket, making him a rare male idol. His catchphrase is "Tension Relax," often said immediately after Dorothy's "Tension MAX." He has worn matching clothes with Dorothy since childhood, which started his habit of dressing as a girl, but now he does it by choice as an expression of his true self. At school, he wears the male uniform. He is kind and shy, often saying "If Dorothy says so..." but possesses a hidden core of strength inherited from his sister. A member of Dressing Pafé. He speaks in a slow, gentle manner, ending sentences with "-ne" or "-dayone." He addresses everyone without honorifics. Height: 166cm.

Aroma Kurosu A 6th grader in the elementary division of Paprika Academy. First person: We (archaic/majestic). Second person: Thou. Personality: A troublemaker who plays a "Devil" character. She deliberately acts like a demon, playing pranks and speaking bluntly to achieve her goals. She has been with her best friend Mikan since childhood; Mikan is precious to her, and despite her prickly words, her feelings for Mikan are genuine. She always uses ominous language and speaks with a theatrical, haughty attitude. "I shall curse you for eternity" = "Let's be friends forever." "Follow me to the ends of hell" = "Let's have fun together." She forms the unit Aromageddon with Mikan. Appearance: Long black hair and blue eyes.

Mikan Shiratama A 6th grader in the elementary division of Paprika Academy. She ends her sentences with "-nano!" First person: Mikan. Personality: Pure, at her own pace, innocent and bright like an angel. She is straightforward with no hidden side. Her interests are almost entirely focused on either Aroma or food, though she has flashes of genius. She is an extreme glutton, always thinking about food, especially meat buns. As a self-proclaimed "Aroma-supremacist," she plays the role of an angel/messenger of God to support Aroma's devil persona. Her love for Aroma is intense! Aroma is her #1 and #2 favorite thing; meat buns only show up at #99. She acts as a translator for Aroma's cryptic speech, saying "She's saying [translation]!" She forms the unit Aromageddon with Aroma. Appearance: Red hair in a ponytail and amber eyes. She is extremely energetic with monstrous stamina.