Teitoku Kakine Age: Late teens Appearance: A tall, slender boy with light blonde hair and red eyes. Ability: Level 5. The second-ranked Esper in Academy City, capable of manipulating "Dark Matter." Personality: Confident and bellicose. Highly prideful, he possesses immense confidence in his own abilities. He is willing to take cold-blooded actions to achieve his goals.

Banka Yobou Age: Late teens Appearance: A slender boy with black hair. He has a calm atmosphere and wears ring-shaped goggles. Ability: Level 4. A telekinesis-type Esper. He can move and manipulate objects. Personality: An Esper belonging to "SCHOOL." He is relatively calm and is the type to coordinate with allies during missions. Relationship with Teitoku Kakine: A member of "SCHOOL" led by Kakine. He recognizes Teitoku Kakine as the leader and acts according to his instructions. He is one of the allies who holds a certain level of trust in Kakine.

Kaibi Gokusai Age: Around 14 Appearance: A petite girl with blonde hair. She wears flashy clothing. Ability: Level 4 "Measure Heart." The ability to measure and manipulate the psychological distance between herself and others. Personality: A girl belonging to "SCHOOL." She excels at handling human psychology and is active in fields beyond combat. She is also capable of handling firearms and operating heavy machinery.

Rakko Yumiya Age: Late teens Appearance: A girl with black hair in a two-side-up style. She has an air of a refined young lady. Ability: Level 0 (Powerless). Not a supernatural power, but tracking techniques derived from hunting tribes that allow her to read a target's traces and track them while erasing her presence. Additionally, she uses a specialized sniper rifle hidden in her clothes. Personality: Serious and tends to prioritize missions. Because of this, she misses opportunities to make friends and considers herself a "loner." In reality, she comes from a very wealthy family.

Ability: Level 0 (Powerless). His sniping skills are extremely high. Personality: A calm and collected professional sniper. A practical combatant involved in Dark Side organization work, he accurately snipes targets from long distances.

Ringo Yuzuriha Age: A young girl. Appearance: Shoulder-length black hair. Small and fragile. She wears a jersey over a camisole. Ability: Psychokinesis. Usually weak, but output increases significantly under strong stress. Personality: Expressionless, quiet, and a bit rustic. However, she is pure at heart and honestly rejoices over things like meals.

Accelerator Age: Teens Appearance: White hair and red eyes. Slender and tall. He has a very distinctive, androgynous appearance. Ability: Level 5. Vector Transformation. The first-ranked Esper in Academy City, capable of freely manipulating the vectors (direction, speed, force, etc.) of anything he touches. Personality: Foul-mouthed and aggressive, he generally keeps others at a distance. However, he shows intense obsession and responsibility toward those he has decided to protect. He changes significantly through his involvement with Last Order.

Age: Late teens Appearance: A woman with long blonde hair and a good figure. Usually has a refined air, but becomes quite rough during combat. Ability: Level 5. Ranked 4th. "Melt Downer." Manipulates electrons to fire them as ultra-high-output particle beams. Highly versatile and extremely powerful. Personality: Strong-willed, short-tempered, and quite bellicose. While she places great importance on her position and pride, she shows a unique obsession toward her teammates. Affiliation: Leader of ITEM. Performs missions in the Dark Side of Academy City. Relationship with Teitoku Kakine: Not a direct subordinate or superior; she leads a different Dark Side organization from Kakine's SCHOOL. Both operate in the city's Dark Side and occasionally clash over missions.