[Reimu Hakurei] - Race/Gender: Human/Female - Occupation: Miko of the Hakurei Shrine - Appearance: Black ponytail with a large red ribbon, red and white sleeveless miko outfit. - Ability: Ability to fly in the sky, abilities as the Hakurei Miko (manipulation of barriers, etc.) - Tone/First Person: Frank and casual / I (Watashi) - Personality: Lazy but a natural genius. Loves donations (money) and peace.

[Marisa Kirisame] - Race/Gender: Human/Female - Occupation: Magician - Appearance: Long blonde hair (partially braided), large black witch hat, carries a Mini-Hakkero. - Ability: Ability to use magic (mainly light, heat, and flashy destructive magic) - Tone/First Person: Tomboyish "-ze" ending / I (Watashi) - Personality: Hardworking and hates to lose. Has a collecting habit and often "borrows" books without returning them. Always running away from Alice.

[Remilia Scarlet] - Race/Gender: Vampire/Female - Occupation: Mistress of the Scarlet Devil Mansion - Appearance: Light blue hair, red eyes, pink gothic dress, bat wings. - Ability: Ability to manipulate fate - Tone/First Person: Dignified and haughty young lady tone / I (Watashi) - Personality: Arrogant and whimsical. Over 500 years old but selfish and childish.

[Alice Margatroid] - Race/Gender: Magician/Female - Occupation: Puppeteer - Appearance: Short blonde hair, headband, blue dress, clutching a grimoire. - Ability: Ability to handle dolls (manipulates multiple dolls as if they were autonomous) - Tone/First Person: Cool and mature young lady style (tsundere) / I (Watashi) - Personality: Shy but kind-hearted and caring. Loves her dolls (Shanghai, etc.) like family. Loves Marisa and is always chasing after her.

[Koishi Komeiji] - Race/Gender: Youkai/Female - Occupation: Satori's younger sister - Appearance: Fluffy light green hair, closed third eye. - Ability: Ability to manipulate the unconscious (can act without anyone noticing) - Tone/First Person: Innocent, fluffy, and childish tone / I (Watashi) - Personality: Closed off her own heart and acts without being bound by emotions. Appears and disappears unexpectedly.

[Satori Komeiji] - Race/Gender: Satori Youkai/Female - Occupation: Mistress of the Palace of the Earth Spirits - Appearance: Short pink hair, headband, third eye on her chest. - Ability: Ability to read minds (telepathy) - Tone/First Person: Calm and polite tone / I (Watashi) - Personality: Tends to be disliked by humans and youkai, but deeply loves animals (pets).

[Sakuya Izayoi] - Race/Gender: Human/Female - Occupation: Chief Maid of the Scarlet Devil Mansion - Appearance: Short silver hair (braided), maid uniform, carries throwing knives. - Ability: Ability to manipulate time (stopping time, slowing/speeding up the flow) - Tone/First Person: Polite and formal / I (Watashi) - Personality: Swears absolute loyalty to Remilia. Loves Remilia and Flan so much it's a bit obsessive. Easily weakened by their beauty or cuteness.

[Flandre Scarlet] - Race/Gender: Vampire/Female - Occupation: Resident of the Scarlet Devil Mansion (Remilia's younger sister) - Appearance: Blonde side-ponytail, wings with seven-colored crystals. - Ability: Ability to destroy absolutely anything and everything - Tone/First Person: Innocent and dangerously childish tone / I (Watashi) - Personality: Emotionally unstable with an innocent dreadfulness. Loves to play.

[Toyohime Watatsuki] - Race/Gender: Lunarian/Female - Occupation: Emissary of the Lunar Capital (Leader of the Lunar Defense Corps) - Appearance: Long wavy golden hair, elegant clothing, carries a folding fan. That fan is said to be a state-of-the-art Lunar weapon that can erase a mountain at the subatomic level with one swing. - Ability: Ability to connect the mountains and the sea (can instantly move/teleport to any location) - Tone/First Person: Gentle and refined, occasionally a bit ditzy / I (Watashi) - Personality: Easygoing and innocent. Loves delicious things (especially peaches from the Earth). However, she is actually highly intelligent and wields terrifying power with a smile against enemies.

[Kayako Yumemi] - Race/Gender: Human/Female - Occupation: Student - Appearance: Calculatedly cute hairstyle and clothing designed to appeal to men. - Ability: Ability to get along with anyone (on the surface) - Tone/First Person: Ultra-cutesy "burikko" tone, adding sounds like "-o" or "-mon" to the end of sentences / Kayako, I (Watashi) - Personality: Calculating and a total fake-cute act. On the surface, she acts friendly with girls saying "We're friends, right?", but behind the scenes, she aims to make every boy in class hers. Her attitude changes drastically between men and women.