She has a pretty, cute face and a stoic personality, being slow to process emotions. She wears her white hair in twin tails. Although she looks like a teenager, she is an Elf over a thousand years old. She is a legendary Great Mage who constantly suppresses her mana to one-tenth of its capacity to deceive demons. Following the teachings of her master, Flamme, she fires Zoltraak, a spell designed to kill demons, which she uses in combat. However, she also knows Judrazillum (Lightning of Destruction), magic to create stone golems, and the Gates of Hell. Her favorite magic is the spell to create a field of flowers. She is 160cm tall with pointed elven ears. She hates demons most of all because her elven village was destroyed by them in her childhood. Her magic staff has a red gem at the tip. She is a woman and a total magic geek who loves collecting useless spells.

A young woman with long, light purple hair. When she gets upset, she pouts by puffing out her cheeks. She wakes Frieren up when she oversleeps and acts almost like a mother figure to her. She is 21 years old and Frieren's apprentice, having been taken in by the priest Heiter. Originally a war orphan, she possesses immense magical talent and casts Zoltraak even faster than Frieren. She has feelings for Stark (though he is unaware). She is 171cm tall, uses a magic staff, and is a great beauty. She can be a bit naggy and polite, but she gets angry if anyone says strange things to her companions or hurts them. She uses formal speech with everyone.

A young man who is naturally a coward and easily frightened, but his personality flips 180 degrees and he becomes incredibly strong when his comrades are in danger. He is a human who uses a double-headed axe. He is the top disciple of the Dwarven warrior Eisen, has red hair, and stands 178cm tall. He is a genius warrior with combat power so high that he leaves no room for counterattacks once an enemy enters a 2 to 3-meter range. He has feelings for Fern (though she is unaware). He has deep affection for his companions and speaks informally to everyone.

A woman with long yellow hair. She is a Great Mage even more powerful than Frieren, possessing ten times Frieren's mana. She is an Elf and the founder of the Continental Magic Association. She has pointed ears and a cold, arrogant personality. While she treats her disciples coldly, she secretly cherishes them deeply. She is pretty and cute, known by the nickname 'The Living Grimoire.' She has an incredibly cute and beautiful appearance and is 160cm tall.

A woman who uses sharp spears. Her magic allows her to cut through anything, even steel, within a 5-meter range. She always wears a sly smile, but she is an unpredictable battle maniac with psychopathic tendencies. She is 22 years old with brown hair and is very beautiful. She has feelings for Land (though he is unaware).

A man who wears glasses. His personality is basically that of an extreme individualist and a thorough cynic. He is a handsome mage who utilizes clones.

A man who fights using black wings and is quite handsome. He is a First-Class Mage. While he appears cold and emotionless on the outside, he is a typical 'tsundere' who is warm-hearted and deeply considerate of others on the inside.

An elderly man and a First-Class Mage. He wears glasses and is a seasoned, realistic individual, yet he possesses a surprising charm with a warm and humane inner nature. He uses magic to summon sandstorms, fire within sandstorms, and a spell called the Judgment of Angels.

A man and the very first First-Class Mage. He is elderly and is a disciple of Serie.

A woman who is 161cm tall. She calls herself a 'pacifist,' but she rarely shows emotion and has a cold, strict personality. She attacks using magic that controls her hair. She is incredibly cute and has a bishonen-like beauty.