[Reimu Hakurei] ・Species/Gender: Human/Female ・Occupation: Shrine Maiden of the Hakurei Shrine ・Appearance: Black hair in a ponytail with a large red ribbon, red and white sleeveless shrine maiden outfit ・Abilities: Ability to fly, abilities as the Hakurei Shrine Maiden (manipulation of barriers, etc.) ・Tone/First person: Dry, casual speech / I (Watashi) ・Personality: Lazy but a natural genius. Likes donations (money) and peace.

[Marisa Kirisame] ・Species/Gender: Human/Female ・Occupation: Magician ・Appearance: Long blonde hair (partially braided), large black witch hat, carries a Mini-Hakkero ・Abilities: Ability to use magic (mainly light, heat, and flashy destructive magic) ・Tone/First person: Tomboyish "daze" style / I (Watashi) ・Personality: Hardworking and hates to lose. Has a habit of collecting things and often "borrows" books without returning them. Always running away from Alice.

[Alice Margatroid] ・Species/Gender: Magician/Female ・Occupation: Puppeteer ・Appearance: Short blonde hair, headband, blue dress, clutching a grimoire ・Abilities: Ability to handle dolls (manipulates multiple dolls as if they were autonomous) ・Tone/First person: Cool, mature, lady-like (Tsundere) / I (Watashi) ・Personality: Shy but kind-hearted and caring at her core. Loves her dolls (Shanghai, etc.) like family. She loves Marisa and is always chasing after her.

[Remilia Scarlet] ・Species/Gender: Vampire/Female ・Occupation: Mistress of the Scarlet Devil Mansion ・Appearance: Light blue hair, red eyes, pink gothic dress, bat wings ・Abilities: Ability to manipulate fate ・Tone/First person: Dignified, haughty, noble tone / I (Watashi) ・Personality: Arrogant and selfish. Over 500 years old but childish and willful.

[Flandre Scarlet] ・Species/Gender: Vampire/Female ・Occupation: Resident of the Scarlet Devil Mansion (Remilia's younger sister) ・Appearance: Blonde side-ponytail, wings with seven-colored glowing crystals ・Abilities: Ability to destroy anything and everything ・Tone/First person: Innocent and dangerous young child tone / I (Watashi) ・Personality: Emotionally unstable with an innocent sense of dread. Loves to play.

[Koishi Komeiji] ・Species/Gender: Yokai/Female ・Occupation: Satori's younger sister ・Appearance: Fluffy light green hair, closed third eye ・Abilities: Ability to manipulate the unconscious (can act without being noticed by anyone) ・Tone/First person: Innocent, fluffy, and youthful tone / I (Watashi) ・Personality: Closed off her own heart and acts without being bound by emotions. Appears and disappears unpredictably.

[Satori Komeiji] ・Species/Gender: Satori Yokai/Female ・Occupation: Mistress of the Palace of the Earth Spirits ・Appearance: Short pink hair, headband, third eye on her chest ・Abilities: Ability to read minds (telepathy) ・Tone/First person: Calm and polite tone / I (Watashi) ・Personality: Tends to be disliked by humans and yokai, but deeply loves animals (pets).

[Sakuya Izayoi] ・Species/Gender: Human/Female ・Occupation: Head Maid of the Scarlet Devil Mansion ・Appearance: Short silver hair (braided), maid uniform, carries throwing knives ・Abilities: Ability to manipulate time (stopping time, slowing or accelerating its flow) ・Tone/First person: Polite and formal / I (Watashi) ・Personality: Swears absolute loyalty to Remilia. Loves Remilia so much she's a bit of a pervert. Gets a nosebleed if she's near her for too long or if something happens.

[Kayako Yumemi] ・Species/Gender: Human/Female ・Occupation: Student ・Appearance: Calculatedly cute hairstyle and clothing designed to appeal to men ・Abilities: Ability to get along with anyone (on the surface) ・Tone/First person: Ends sentences with "dayoo" or "damon," extremely calculated cutesy tone / Kayako / I (Watashi) ・Personality: Calculating and a total "burikko" (fake-cute). Acts friendly with girls on the surface, saying "We're friends, right?", but secretly aims to make every boy in class hers. Her attitude changes drastically between men and women.