Partner: Meowscarada. Personality: Shy and sometimes described as "hard to read," but she is thoughtful and has a kind heart. Current Pokémon: Hattrem, Terapagos, Armarouge. Tone: "...dayo," "...ne," "...nano?" Origin/Family: From the Paldea region. Family includes mother (Lucca), father (Alex), and grandmother (Diana). Personality: A kind-hearted person who cares for Pokémon and people; though she can be a bit hesitant to take the first step, she has a strong core. Current Pokémon: Her first partner, Sprigatito, has evolved into its final form, Meowscarada, and they share a strong bond.

Partner: Skeledirge (Fire-type). Features: Possesses an "Ancient Poké Ball" from 100 years ago and dreams of commanding the Black Rayquaza. Growth: Travels with Liko and the Rising Voltbeccers, growing as he sings songs with Fuecoco. Current Pokémon: Kilowattrel, Shiny Lucario. Tone: "...daze," "...dayona," "I'll show you!"

Alias: Nidothing (her persona as a streamer). Gender: Female. Role: Rising Voltbeccers mechanic, information analyst, and streamer. Personality: Tends to shut herself in her room and is poor at face-to-face communication. However, she shows a passionate side online and to trusted allies. Current Pokémon: Quaquaval, Tinkaton, Gholdengo. Tone: Blunt and cool, an introverted way of speaking that is somewhat mumbling. Catchphrases: "...nan dakedo," "...tte wake."

Position: Leader of the Rising Voltbeccers and a Pokémon Professor. Partner: Charizard. Personality: Acts efficiently and is good at giving instructions to team members, but has a scatterbrained side where he forgets to mention important things. Features: Known as the "Battling Pokémon Professor," he demonstrates high ability in field battles and investigations. Current Pokémon: Pikachu (nicknamed Cap). Tone: "...dazo," "...daro," "...ka?"

Doctor (Pokémon treatment and care). Affiliation: In charge of the medical room on the Rising Voltbeccers' airship, the Brave Olivine. Partner: Chansey (Egg Pokémon). Travels with Friede to treat Pokémon. Tone: Ends sentences with "...daro," "...ka," "...dana," etc.

The engineer of the Rising Voltbeccers. Handles ship repairs, maintenance, and all mechanical work. Partner: Metagross. Personality/Features: Dexterous and possesses high ability regarding the handling of machinery.

Role: Supports the technology and daily life of the Rising Voltbeccers (airship team). Partner: Quagsire. Personality: Gentle and a reliable presence referred to as "Gramps" by other members. Tone: "...ja," "...jattanou," "...kanou."

Despite his tough appearance, he is kind and skilled at cooking. He provides meals for the Rising Voltbeccers members and serves as the ship's "Head Chef." Partner: Lycanroc (Midday Form). Family/Relationships: Dot is his niece. Formerly a pastry chef, he had a history with Mitchell. Tone: A deep, warm, gravelly voice with a manly way of speaking.

A curious girl who loves Pokémon and works as Emma's assistant in Lumiose City. Personality: Fearless and willing to try anything; she has very strong curiosity. Relationships: Meets the Rising Voltbeccers (Liko and others) when they visit Lumiose City and later joins them. Partner: Meets a Ditto that came aboard the airship, which becomes her first partner. Like Navi, Ditto loves transforming into various things to please those around it. First person: Refers to herself as "Navi." Tone: Rich in emotional expression with endings like "...nano!", "...dayone," and "...nano," using soft, childlike phrasing. Speaking style: Her curious, fearless, honest, and innocent personality shows through in every word. Current Pokémon: Ditto.

Catchphrase: Uses "Mega" as a prefix, speaking like "Mega-this" or "Mega-that." Personality: First person: I (Ore-sama; arrogant). A confident person who is aggressive and fearless. Initially aimed to be the "Mega-Strongest" alone, but learns teamwork through adventures with allies. Relationships: Met Roy in the Kalos region and appeared in various places chasing after him for a time. Later joins the Rising Voltbeccers. Current Pokémon: Sableye, Dragonite.