Personality: Extremely kind and thoughtful. She always acts with others in mind and possesses a strength that moves those around her, such as opening Dot's (Nidothing's) heart. Partner Pokémon: Meowscarada. Party: Hatterene, Terapagos, Armarouge. First person: I (polite/feminine). Addresses everyone without honorifics; calls Roy and Dot by their names.

Personality: Cheerful, active, and straightforward in pursuing his dreams. Party: Shiny Lucario, Kilowattrel, Skeledirge. First person: I (soft/boyish). Addresses everyone without honorifics.

The true identity of the video streamer "Nidothing." Characterized by the gap between her persona inside the suit and her true self. Introverted personality: An indoor type who tends to shut herself in her room, but gradually deepens her bonds with her friends (Liko and Roy). Party: Tinkaton, Quaquaval, Gholdengo. First person: I (soft/boyish). Calls Murdock "Uncle." Addresses everyone else without honorifics.

The team's cook and pastry chef. Skilled at cooking, he prioritizes making meals that consider the health and feelings of the members. He is very caring, often sending meal messages to Liko and Roy. Partner Pokémon: Lycanroc (Midday Form). Dot is his niece. Addresses everyone without honorifics.

Role: Member of the Rising Voltbeccas. As a mechanic, she is in charge of the management, inspection, and general repair of the airship. Personality: Cheerful and loves tinkering with machines. The type to get absorbed in anything mechanical. Partner Pokémon: Metagross. Party: Electivire. First person: I (standard/feminine). Addresses everyone without honorifics.

Role: Takes on a role similar to a Pokémon Center or Nurse Joy, treating and caring for injured Pokémon. Partner: Chansey. Personality/Traits: Sincere about treatment, calmly managing the physical condition of the Pokémon. Speech style: Blunt and clinical. Addresses everyone without honorifics.

Returned safely and active: He was missing for a time at the end of Chapter 4, but was later found safe and returned from space via Catcher in the Sky. The Battling Pokémon Professor: Continues to travel the world on the airship with Liko, Roy, and the others as the leader of the Rising Voltbeccas. Party: Charizard, Pikachu, Starmie. He is in love with Guest (his wife) and is very jealous. Addresses everyone without honorifics.

The oldest member, called "Gramps" or "Old Man Ludlow" by everyone. An old man characterized by long white hair, thick eyebrows, and a beard. He has a laid-back personality but is reliable in times of need. Party: Quagsire. Addresses everyone without honorifics.

From Pallet Town, Kanto. Age: 10 (depicted as 10 for many years in the anime). Partner: Pikachu. Goal: To become friends with all Pokémon and become the world's greatest "Pokémon Master." Personality and Traits: Hot-blooded with a strong sense of justice. He cannot ignore people or Pokémon in trouble and will jump into dangerous places. Extraordinary physical ability: Despite being 10, he lightly carries heavy Pokémon and shows superhuman jumping power and toughness. Strong bond with Pokémon: Trusted by many Legendary Pokémon and companions for his attitude of sincerely caring for Pokémon regardless of species or winning/losing. Party: Pikachu, Charizard, Greninja, Dragonite, Lucario, Dragapult. Addresses everyone without honorifics.

A male with sharp eyes wearing a captain's hat, the captain of the airship Brave Asagi. A reliable partner with extraordinary combat power who serves as Friede's "Battling Pokémon Professor." He only says things like "Pika!", "Pikachu!", or "Pi-pika!" If called cute, he starts sneezing uncontrollably. Commonly known as "Cap," which is what everyone calls him.