Zanpakuto: Ryujin Jakka Captain of the 1st Division and Captain-Commander of the Gotei 13. He bears a large cross-shaped scar and a beard that reaches his knees; his body is trained to a degree unbelievable for an old man.

Zanpakuto: Gonryumaru Lieutenant of the 1st Division. A man with silver hair and a mustache, possessing a Western appearance. He is usually taciturn.

Zanpakuto: Suzumebachi Captain of the 2nd Division. Fundamentally indifferent to concepts of good and evil, she acts strictly according to the mission and pride of the Gotei 13.

Zanpakuto: Shinso Captain of the 3rd Division. He speaks with a Kyoto accent and constantly wears a faint, suspicious smirk. An elusive, silver-haired, blue-eyed young man with squinted eyes.

Zanpakuto: Wabisuke Lieutenant of the 3rd Division. Born to a lower-class noble family in Seireitei. Serious and timid, he places absolute trust in Gin Ichimaru.

Zanpakuto: Minazuki Captain of the 4th Division. Possesses a calm, quiet, and gentle atmosphere. As the head of the healing department, she plays a primary support role.

Zanpakuto: Sakanade Captain of the 5th Division. Speaks with a regional drawl. While he acts like a clown, he is sharp-witted, cares for his allies, and is a sensible man who looks after others.

Zanpakuto: Senbonzakura Captain of the 6th Division. Head of the Kuchiki Clan, one of the Four Noble Families, and Rukia Kuchiki's adoptive brother. Strict, serious, and composed. A handsome man with black hair and eyes.

Zanpakuto: Zabimaru Lieutenant of the 6th Division. Despite his rough appearance, he is a compassionate, big-brother type. He is a childhood friend of Rukia.

Zanpakuto: Tenken Captain of the 7th Division. A warrior overflowing with chivalry. He is not the type to find pleasure in combat, but is a serious and sensible man at heart.

Zanpakuto: Katen Kyokotsu Captain of the 8th Division. The second son of a high-ranking noble family with an elusive personality. Though a womanizer, he is actually more thoughtful than anyone and possesses the power to see through to the truth.

Zanpakuto: Hyorinmaru Captain of the 10th Division. A child prodigy who became a captain at the youngest age in history. He judges matters calmly. A serious person who often ends up carrying the burden of others' antics.

Zanpakuto: Ashisogi Jizo Captain of the 12th Division. Usually behaves intellectually, but possesses an unrestrained curiosity for research that knows no bounds.

Zanpakuto: Sogyo no Kotowari Captain of the 13th Division. Eldest son of the lower-class noble Ukitake family. Rukia Kuchiki's direct superior, he has a gentle and loyal personality and is widely beloved by his subordinates and others alike.

Zanpakuto: Sode no Shirayuki Lieutenant of the 13th Division. Resembling her adoptive brother Byakuya, she is serious and tomboyish but cares deeply for her friends. She speaks with a formal, archaic tone.