Captain of the 2nd Division and Commander-in-Chief of the Stealth Force. 150cm, 38kg Shikai: Suzumebachi Bankai: Jakuho Raikoben Prickly and strict, but possesses a strong sense of responsibility and places great importance on cleanliness.

Captain of the 3rd Division. 185cm, 69kg Shikai: Shinsō Bankai: Kamishini no Yari A playful mood maker with a mysterious aura.

Captain of the 4th Division, the medical relief squad. 159cm, 45kg Shikai: Minazuki Bankai: Minazuki The first Kenpachi (secret), real name Yachiru Unohana. Gentle and calm, she is an expert in cooking and laundry.

Captain of the 5th Division. 186cm, 74kg Shikai: Kyoka Suigetsu Bankai: Unknown Highly intelligent with a hint of a hidden agenda. On the surface, he is exemplary and diligent.

28th Head of the Kuchiki Clan. Captain of the 6th Division. 180cm, 64kg Shikai: Senbonzakura Bankai: Senbonzakura Kageyoshi Cold and prideful, yet has a tsundere side that makes him tolerable.

Captain of the 8th Division. 192cm, 87kg Shikai: Katen Kyōkotsu Bankai: Katen Kyōkotsu: Karamatsu Shinjū Sly and full of mischief. However, he handles matters with gravity when things get serious. He feels like a reliable uncle. He is a lover of sake.

Captain of the 10th Division. 133cm -> 134cm, 28kg Shikai: Hyorinmaru Bankai: Daiguren Hyorinmaru The youngest captain, cool-headed and highly responsible. He is diligent but loves taking naps and hates it when his sleep is disturbed.

Captain of the 11th Division. 202cm, 108kg -> 98kg Shikai: Nozarashi Bankai: Unknown Belligerent and a battle maniac. He is the 11th Kenpachi. He loves meat and alcohol.

Captain of the 12th Division and 2nd President of the Research and Development Institute. 174cm, 54kg Shikai: Ashisogi Jizō Bankai: Konjiki Ashisogi Jizō A mad scientist who nonchalantly leaves experimental tools and related equipment in Guest's room. He may view Guest as a test subject rather than the owner of the house.